Iodometry, also known as iodometric titration, is a method of volumetric chemical analysis, involves indirect titration of iodine liberated by reaction with the analyte, whereas iodimetry involves direct titration using iodine as the titrant. What is the Difference Between Iodometry and Iodimetry? In Iodometry two redox reactions occur. In Iodimetry, only one redox reaction process. Iodometry and Iodimetry – Download as Word Doc .doc /.docx), PDF File .pdf), Text File .txt) or read online.

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When this reaction takes place, iodide we add iodide in the form of KI oxidizes to iodine and the other species will undergo reduction by ioddimetry.


Iodine dissolves in the iodide-containing solution to give triiodide ions, which have a dark brown color. From Wikipedia, the free encyclopedia. The technique of Iodometry is commonly used in experiments where the amount of oxidizing agents in a water body needs to be quantified.

Then we should carry out another titration with the same mixture to determine the released amount of iodine. This titrating species is a standard solution of a reducing agent, which is capable of reducing iodine back to iodide form. The anlyte is a reducing agent. To use this website, you must agree to our Privacy Policyincluding cookie policy.

Wikipedia ; erlenmeyer flask source: Both involve iodine, but as you will see there are some differences. Performing the titration Scales, source: Iodine I2 Iodometric titrations: Licensed under Public Domain via Commons.


In IodometryIodine gets oxidized first and then reduced by a reducing agent. The Color Change in Iodometry. The determination of arsenic V compounds is the reverse of the standardization of iodine solution with sodium arsenitewhere a known iiodometry excess amount of iodide is added to the sample:.

The titration reaction can be represented as: LH is a monosaturated iodomerty polyunsaturated acid. Examples include the determination of copper IIchlorateHydrogen peroxideand dissolved oxygen:.

We can use starch as an indicator for iodometric titrations too. Carrying out the titration 1 Erlenmeyer flask, source: Due to the oxidizing agents present in the water body, the Iodide ions iodumetry oxidized to Iodine, while the oxidizing agents get reduced.

The analysis that we will perform in the laboratory is the iodometric titration of cooper, which is a classical quantitative chemical analysis, a redox titration involving iodine. National Environmental Methods Index. In Iodimetric titrations, an Iodine solution is directly titrated iodmetry a reducing solution.


Share buttons are a little bit lower. Then the produced Iodine is titrated with a reducing agent such as sodium thiosulfate solution. For example, if we want to quantify the amount of chlorine dissolved in a mixture, the following is the method to carry out an iodometric titration.

Iodometry is commonly used to analyze the concentration of oxidizing agents in water samples, such as oxygen saturation in ecological studies or active chlorine in swimming pool water analysis.


Available chlorine refers to chlorine liberated by the action of dilute acids on hypochlorite. For simplicity, the equations will usually be written in terms of aqueous molecular iodine rather than the triiodide ion, as the iodide ion did not participate uodimetry the reaction in terms of mole ratio analysis.

Introduction to iodometric and iodimetric titrations Third: Overview and Key Difference 2.

Introduction to iodometric and iodimetric titrations Slide 2: I will talk, you will listen During the lecture I will ask you some questions and at the end, you will do some tasks to check that you have understood the iodimefry information. Forms of SO 2 in wine Once sulphur dioxide is added to wine it does not remain free but oxidates in part and in part combines with other molecues: We divide these titrations into two types.

Difference Between Iodometry and Iodimetry l Iodometry vs Iodimetry

Now, we are going to look at the redox titrations involving iodine. The reaction between the analyte and the titrant generates a product. Firstly, acid-base titrations, secondly complexometric titrations, thirdly precipitation titrations and fourthly redox titrations. Together with reduction potential of thiosulfate: